An Introduction to Materials Engineering and Science.pdf

AN INTRODUCTION TO

MATERIALS ENGINEERING

AND SCIENCE

AN INTRODUCTION TO

MATERIALS ENGINEERING

AND SCIENCE

FOR CHEMICAL AND

MATERIALS ENGINEERS

Brian S. Mitchell

Department of Chemical Engineering,

Tulane University

A JOHN WILEY & SONS, INC., PUBLICATION

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Library of Congress Cataloging-in-Publication Data:

Mitchell, Brian S., 1962-

An introduction to materials engineering and science: for chemical and materials engineers

Brian S. Mitchell

p. cm.

Includes bibliographical references and index.

ISBN 0-471-43623-2 (cloth)

1. Materials science. I. Title.

TA403.M685 2003

620.1 1—dc21

2003053451

Printed in the United States of America.

10987654321

To my parents; whose

Material was loam;

Engineering was labor;

Science was lore;

And greatest product was love.

CONTENTS

Preface

Acknowledgments

1 The Structure of Materials

1.0 Introduction and Objectives

1.1 Structure of Metals and Alloys

1.2 Structure of Ceramics and Glasses

1.3 Structure of Polymers

1.4 Structure of Composites

1.5 Structure of Biologics

114

References

128

Problems

130

2 Thermodynamics of Condensed Phases

136

2.0 Introduction and Objectives

136

2.1 Thermodynamics of Metals and Alloys

140

2.2 Thermodynamics of Ceramics and Glasses

165

2.3 Thermodynamics of Polymers

191

2.4 Thermodynamics of Composites

200

References

209

Problems

211

3 Kinetic Processes in Materials

215

3.0 Introduction and Objectives

215

3.1 Kinetic Processes in Metals and Alloys

219

3.2 Kinetic Processes in Ceramics and Glasses ∗

233

3.3 Kinetic Processes in Polymers

246

3.4 Kinetic Processes in Composites ∗

269

3.5 Kinetic Processes in Biologics ∗

277

References

280

Problems

282

4 Transport Properties of Materials

285

4.0 Introduction and Objectives

285

4.1 Momentum Transport Properties of Materials ∗

287

vii

2.5 Thermodynamics of Biologics

204

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