Crystallization Processes in Fats and LipidSystems + N. arti, K. Sato.pdf

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ISBN: 0-8247-0551-3
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Preface
More than 10 years ago we published our first book, Crystallization and Polymor-
phism of Fats and Fatty Acids . The book presented the basic concepts and tech-
niques available at that time associated with the physical behavior of fats and
oils with relation to their crystallization and polymorphic transformations. The
book was well accepted by the scientific community as well as by technologists
and engineers.
Significant progress has been made in recent years in this research area,
both in fundamental aspects of crystallization and in applications. We felt that
it was an appropriate time to update our book with relevant new developments
in the area. Of special interest are the advanced analytical tools such as the micro-
probe techniques, high-power Synchrotron radiation X-ray diffraction, vibra-
tional spectroscopy and infrared adsorption, Raman scattering and nuclear mag-
netic resonance, computer modeling, and sophisticated calculations. These ad-
vanced techniques have provided significant new information resulting in cutting-
edge research and a better understanding of molecular structures, morphology
and texture of fats and lipids, kinetic-phase properties of phase transformations,
mixing behavior, and interactions with seeding materials, especially with surfac-
tants.
The past 10 years have brought new aspects and new concepts of fat crystal-
lization and polymorphism of new fats, complex blends of specialty fats, fatty
acids, non-saponifiable lipids and mono- and diglycerides. This book is bringing
to light new and emerging techniques, processes, and mechanisms, stressing what
is new and different, promising and revolutionary. We are strongly impressed by
the new dimensions that some scientists have brought to this field. Interfacial
crystallization in emulsions and microemulsions, lyotropic liquid crystals, and
other self-assembled structures are only some of these new areas. Crystallization
iii
iv
Preface
in confined volumes is an innovative approach that leads to interesting options
for preparation of nano-sized crystals with unique properties, as well as new
polymorphic forms that are interfacially mediated. Other promising studies are
related to pharmaceuticals, cosmetics, and food applications.
Lipids and fats are drawing strong attention from nutritionalists and life
science researchers. The needs for specialty fats and oils with strong emphases
on health, balanced nutrition, and functionality are a strong motivation for better
selection of fat blends in the solid form. These dictate narrow particle sizes,
flowing properties, and new physical properties derived from a better control of
polymorphism and crystallization. Industrial crystallization of fats and lipids is
an important issue mainly for food applications. Some progress has also been
made in this area.
We believe that this new book brings a well-balanced structure of funda-
mental and applied developments to the field of fats and lipids crystallization. We
hope that the reader will enjoy this book, as well as find it useful and rewarding.
Nissim Garti
Kiyotaka Sato
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