final_work.doc

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FAME (Fatty Acid Methyl Ester) reaction unit works continuously with stream of reagents and catalyst mixture.  Chemical reaction is presented underneath:

Where

Table 1. R – alkyl radicals and densities

radical

source (approx.) and name

density [g/cm3] (at 20 oC)

trigliceride

ester

-C17H33

RME (Rapeseed Methyl Ester)

0.900

0.867

-C17H31

SFME (SunFlower Methyl Ester)

0.902

0.871

-C17H29

FME (Flax Methyl Ester)

0.916

0.897

Methanol density d=0.7918 g/cm3

Sulfuric acid density d=1.8356 g/cm3

Glycerol density d=1.2589 g/cm³

Construct model for description of flow reactor with specified output of ester. Draw flowchart and make necessary calculations of reagent flows basing on output stream of ester as well as reactor volume. Flowchart specification:

·         alcohol tank

·         fatty acid tank

·         base feeder

·         mixer

·         reactor

·         separator of methanol (distiller – assume 100% effectiveness)

·         separator of glycerol (

·         recirculation is unnecessary

Methanol is introduced to the mixture with the excess in the reference to stoichiometry to improve of the reaction.

Simplifying assumption: densities of reagents are the same in different temperature (cause: lack of data)

Data for project are given in Table 2.


Table 2. Data for the project

No.

name

contact time

temp.

 

alcohol excess

catalyst

yield

ester output

[min.]

[oC]

%

comp.

mass concentr. [%]

[%]

dm3/h

1

RME

60

35

7

NaOH

2.5

88

15

2

SFME

60

35

6.5

NaOH

2.25

86

20

3

FME

60

53

6

NaOH

2.0

85

25

4

RME

70

38

8

KOH

2.1

85.5

30

5

SFME

70

38

7

KOH

2.0

84.8

...

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